Brepresents
the number of moles of NaOH added at the specific point in the titration so bis equal to the number of moles of
NaOH present at a certain pH and is calculated using C=b*v rearranged to c*v=b.
c= concentration of NaOH and v=volume of NaOH added at that point.Arepresents
the number of moles of the initial acid in the beaker and is calculated by;
c*v=a. C is the concentration of the
acid and v is the volume=0.04*0.025=0.001 moles.The data was then plotted as a graph for pH against Log10(b/a-b);The slope and intercept can then be calculated to deduce
the pH of the solution when x=0 to give the pKaof the benzoic acid.Y=MX+CM=y2-y1/x2-x1 C=y1-mx1Y2 was the highest pH plotted and y1 the lowest pH record;
x2 and x1 are the corresponding log(b/a-b) values.M=(4.5-2.52)/((-0.0872)-(-1.28))=1.66C=(2.52)-(1.66)*(-1.28)=4.54Y=1.66*0+4.54=4.54Therefore; pKaof benzoic acid is 4.54