The heat capacity is critical in
calculating the enthalpy and entropy. Using the data (heat capacity) from book
or internet and also ?fusH (I2) = 15.52387kJ/mol at 387K
and ?vap
(I2) =41.57kJ/mol at 457K.
a) Calculate the heat required to bring one mole of iodine from 0K to 500k.
b) calculate the absolute entropyof
iodine at 500KConsider the melting of one mole
of water. Use the following data to answer the questions: S?=( H2O
l)=69.9J/K.mol S?( H2O s)=47.8J/K.mol ?H?(
H2O l)=-285.8kJ/mol and ?H?( H2O s)=-298.8kJ/mol.
Assume standard molar entropies and enthalpies of formation are not functions of temperature in this
range. a) calculate the entropy change of the system for melting ice at -5?C.
b) Calculate the entropy change of the surrounding for melting ice at -5?Cand C) Is this reaction spontaneous at -5?C?
Justify.